Cyclopolymerization and Polymers with Chain-Ring Structures by George B. Butler and Jiri E. Kresta (Eds.)
By George B. Butler and Jiri E. Kresta (Eds.)
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Extra resources for Cyclopolymerization and Polymers with Chain-Ring Structures
Macromol. Sci. Chem. 1975, 9, 1113. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. 42 POLYMERS WITH CHAIN-RING STRUCTURES 14. Matsoyan, S. G. J. Polym. Sci. 1961, 52, 189. 15. ; Mitoh, M. J. Polym. Sci. 1965, A3, 2149. 16. Butler, G. ; Miller, W. L. J. Am. Chem. Soc. 1958, 80, 3615. 17. Butler, G. B. J. Polym. Sci. Polym. Symp. 1978, 64, 71. 18. ; Oiwa, M. J. Polym. Sci. Polym. Lett. Ed. 1980,18,211. 19. ; Oiwa, M. J. Polym. Sci. Polym. Lett. Ed. 1980,18,307. 20. ;Oiwa, M.
3 Intramolecular Addition Modes in Radical Cyclopolymerization of Some Unconjugated Dienes AKIRA MATSUMOTO, KUNIO IWANAMI, TAKAO KITAMURA, and MASAYOSHI OIWA Kansai University, Department of Applied Chemistry, Faculty of Engineering, Suita, Osaka 564, Japan GEORGE B. BUTLER University of Florida, Center for Macromolecular Science, Gainesville, FL 32611 The f a c t o r s modes were i n v e s t i g a t e d i n d e t a i l i n the r a d i c a l c y c l o p o l y m e r i z a t i o n of some unconjugated d i e n e s .
The r a t e c o n s t a n t c a l c u l a t e d a t jO°C from p T a b l e IV - E x p e r i m e n t a l a c t i v a t i o n energy and e n t r o p y and r a t e c o n s t a n t a t JO°C f o r t h e c h a i n p r o p a g a t i o n i n the f r e e r a d i c a l p o l y m e r i z a t i o n of b u t y l a c r y l a t e . Ref. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. k P 27 14 579 173 2. GUAiTA Temperature Dependence of Cyclization Ratios 23 t h i s v a l u e o f t h e a c t i v a t i o n e n t r o p y and the c o r r e s p o n d i n g v a l u e Ep = 2 3 .