CRC Handbook of Tables for Organic Compound Identification by Zvi Rappoport
By Zvi Rappoport
Read or Download CRC Handbook of Tables for Organic Compound Identification PDF
Best organic books
Provides the main leading edge leads to carbene chemistry, atmosphere the basis for brand new discoveries and purposes the invention of good carbenes has reinvigorated carbene chemistry study, with investigators trying to boost carbenes into new valuable catalysts and ligands. featuring the main leading edge and promising components of carbene examine over the last decade, this ebook explores newly found structural, catalytic, and organometallic elements of carbene chemistry, with an emphasis on new and rising artificial purposes.
Written via an skilled editor broadly acclaimed in the medical group, this e-book covers every thing from oxygen to nitrogen functionalities. From the contents: Palladium-Catalyzed Syntheses of 5-membered Saturated Heterocycles The Formation of Carbon-Sulfur and Carbon-Selenium Bonds by way of Substitution and Addition Reactions Catalyzed by way of Transition steel Complexes Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes Palladium-Catalyzed Formation of fragrant Heterocycles Rhodium-Catalyzed Amination of C-H-Bonds Transition Metal-Catalyzed Synthesis of Heterocycles Copper-Catalyzed Synthesis of Azoles Palladium(II)-Catalyzed C-N Bond Formation related to Aminopalladation of Aklenes Carbon-Heteroatom Bond Formation through Rh(I)-Catalyzed Ring-Opening Reactions contemporary Advances in Homogeneous Gold Catalysis: Formation of Carbon-Heteroatom Bonds the result's an essential resource of knowledge for the strategic making plans of the artificial routes for natural, catalytic and medicinal chemists, in addition to chemists in undefined.
This moment version includes consise info on 134 rigorously selected named natural reactions - the normal set of undergraduate and graduate man made natural chemistry classes. each one response is exact with essentially drawn mechanisms, references from the first literature, and well-written bills masking the mechanical features of the reactions, and the main points of part reactions and substrate boundaries.
Titanium has been used to accomplish many varieties of reactions in natural and inorganic chemistry. the current booklet is worried essentially with a brand new improvement in titanium chemistry that's worthwhile in natural synthesis. In 1979/80 it was once came upon that the titanation of classical carbanions utilizing C1TiX results in species with diminished basicity and reactivity.
- Molecular Self-Assembly Organic Versus Inorganic Approaches
- The Complete Idiot's Guide to Making Natural Soaps
- Dipole Moments in Organic Chemistry
- Organic Chemistry: Study Guide and Solutions Manual
- Strained Organic Molecules
Extra info for CRC Handbook of Tables for Organic Compound Identification
O R G A N I C D E R I V A T I V E S O F A R O M A T I C H Y D R O C A R B O N S a) Liquids. )* (Continued) Name Boiling Melting point, "C point. 5-Benzindane (1,2-Cyclopentanonaphthalene) n-Dndecylbenzene (1-Phenyldodecane) 1-Heptylnaphthalene 2-Heptylnaphthalene Tridecylbenzene (1 -Phenyltridecane) 1-Octylnaphthalene 2-Octylnaphthalene - 22 -21 -5 - 17 7 -5 6 3 I 10 -2 0 2 forms stable - 0 5, metastable 13 12 *Derivative data given i n order m p ,crystal color, solvent from which crystallized Copyright 1967 by CRC Press, Inc.
Hg salt, 96 7 n-BuOH Handbook of tables for Organic Compound Identification, © 1967 CRC EXPLANATIONS AND REFERENCES TO TABLE IV Nitro derivative ' HNO 3 ArH H2O ArNO 2 Nitro derivative From the aromatic hydrocarbon with concentrated nitric and sulfunc acids For directions and examples see Cheroms, p 578 80, Linstead, p 48, 49, Shnner, p 249, Vogel, p 520, Wild, p 24 From the aromatic hydrocarbon with fuming and concentrated nitric acids See Shnner, p 249, Wild, p 24 From the aromatic hydrocarbon with fuming nitric acid in acetic acid See Vogel, p 520 From the aromatic hydrocarbon with nitric and sulfunc acids in chloroform See Vogel, p 580 Acetamido and Benzamido derivatives ' (CH,CO) 2 0 ArH HNOi ArNO 2 Sn/HCI ArNHCOCH 3 + CH3COOH Acetamido derivative ArNH 2 — C6H5COCI ArNHCOC 6 H 5 + HC1 Benzamido derivative Nitration of the aromatic hydrocarbon is followed by reduction with tin and hydrochloric acid The resulting amine is acetylated with acetic anhydride or benzoylated with benzoyl chloride For directions and examples see Cheroms, p 581, V L Ipatieff and L A Schmerhng, J Amer Chem Soc, 59, 1056(1937), 60, 1476(1938), 65,2470(1943) o-Aroylbenzoic acid (product with phthahc anhydride) a ArH COAr COOH o-Aroylbenzoic acid From the aromatic hydrocarbon, phthahc anhydride and aluminum chloride in carbon disulfide For directions and examples see Cheroms, p 548, Shnner, p 250, Vogel, p 519, Wild, p 28, H W Underwood and W L Walsh, J Amer Chem Soc , 57, 940(1935) From the aromatic hydrocarbon, phthahc anhydride and aluminum chloride without solvent See G F Lewenz and K.
112 76, Nitrosite. 8-m-Menthadieni (I -1sopropenyl-3methylcyclohexene) etra- 135 etra- 104 etra- 137-8, me al -chl etru- 125. eth k- 115 etra- 129-30, pet eth - *Derivative data given in order m p ,crystal color, solvent from which crystallized 23 Copyright 1967 by CRC Press, Inc. 8 105 6 [ale +49 I. 111, Nitrosate, H6d , ac a -me dl T A B L E 11. )* (Continued) Name Boiling point, O C Melting point, O C Menogene (3-lsopropylidene-b-rneth! cyclohexene Terpinolene (4-Isopropyhdene- 1 methylcyclohexene) 2-Undecene (2Hendecene) 5-Undecene (5Hendecene) 1-Undecene ( 1-Undecene) CIS-Cyclodecene Bromine addition product Miscellaneous -Bromo - Aletra- Nitrosite, 155, me al or chl , Maleic anh adduct, 205 8 Maleic anh adduct, 182 2 forms A- -49 19 A- A-35 23 - 0, Sebacic acid, 134 5 A- -23 07 -12 85 A- - 3 73 il- 1 2 A- 12 -2 5 il- 76 dl- Mercaptosuccinic acid adduct, 1040 8 Cedrene 1-Heptadecene 2-Methyl-2-heptadecene 1-Octadecene Derivative data given in order m p ,crystal color, solvent from which crystallized Copyright 1967 by CRC Press, Inc.