Catalyzed Carbon-Heteroatom Bond Formation by Andrei K. Yudin, John F. Hartwig

By Andrei K. Yudin, John F. Hartwig

Written through an skilled editor extensively acclaimed in the clinical group, this ebook covers every thing from oxygen to nitrogen functionalities. From the contents:

  • Palladium-Catalyzed Syntheses of 5-membered Saturated Heterocycles
  • The Formation of Carbon-Sulfur and Carbon-Selenium Bonds by way of Substitution and Addition Reactions Catalyzed through Transition steel Complexes
  • Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes
  • Palladium-Catalyzed Formation of fragrant Heterocycles
  • Rhodium-Catalyzed Amination of C-H-Bonds
  • Transition Metal-Catalyzed Synthesis of Heterocycles
  • Copper-Catalyzed Synthesis of Azoles
  • Palladium(II)-Catalyzed C-N Bond Formation concerning Aminopalladation of Aklenes
  • Carbon-Heteroatom Bond Formation by means of Rh(I)-Catalyzed Ring-Opening Reactions
  • fresh Advances in Homogeneous Gold Catalysis: Formation of Carbon-Heteroatom Bonds

The result's an crucial resource of knowledge for the strategic making plans of the artificial routes for natural, catalytic and medicinal chemists, in addition to chemists in undefined.

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Catalyzed Carbon-Heteroatom Bond Formation

Written by way of an skilled editor largely acclaimed in the medical group, this ebook covers every little thing from oxygen to nitrogen functionalities. From the contents: Palladium-Catalyzed Syntheses of 5-membered Saturated Heterocycles The Formation of Carbon-Sulfur and Carbon-Selenium Bonds through Substitution and Addition Reactions Catalyzed by way of Transition steel Complexes Palladium-Catalysis for Oxidative 1,2-Difunctionalization of Alkenes Palladium-Catalyzed Formation of fragrant Heterocycles Rhodium-Catalyzed Amination of C-H-Bonds Transition Metal-Catalyzed Synthesis of Heterocycles Copper-Catalyzed Synthesis of Azoles Palladium(II)-Catalyzed C-N Bond Formation related to Aminopalladation of Aklenes Carbon-Heteroatom Bond Formation through Rh(I)-Catalyzed Ring-Opening Reactions contemporary Advances in Homogeneous Gold Catalysis: Formation of Carbon-Heteroatom Bonds the result's an quintessential resource of knowledge for the strategic making plans of the artificial routes for natural, catalytic and medicinal chemists, in addition to chemists in undefined.

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1986) J. Chem. , Chem. M. M. (1993) J. Am. Chem. , and Yamamoto, Y. (2003) Heterocycles, 61, 247–257. P. (2007) J. Am. Chem. , 129, 12398–12399. , and Tamaru, Y. (2008) Angew. , Int. , 47, 5803–5805. , and Alper, H. (1995) J. Am. Chem. , and Alper, H. (1994) J. Am. Chem. , 116, 1220–1224. (a) Tamaru, Y. -i. (1987) J. Organomet. , 334, 213–223; (b) Negishi, E. (1992) Pure Appl. , 64, 323–334; (c) Tamaru, Y. and Kimura, M. (1997) Synlett, 749–757; (d) El Ali, B. and Alper, H. , and Costa, M. M. (2004) Tetrahedron, 60, 5499–5538.

9). An oxidant is typically required to regenerate Pd(II) from Pd(0) following reductive elimination. 9 Mechanism for Pd(II)-catalyzed carbonylation of CÀM bonds terminated by OH. 10). Surprisingly, this reaction occurs in the absence of external oxidant because Tl(III) salts generated via transmetallation can reoxidize Pd(0) to Pd(II). Lithium chloride and magnesium oxide were added to suppress (4) j 2 Transition Metal Catalyzed Approaches to Lactones Involving CÀO Bond Formation 40 R H OH n 10 mol% PdCl , 2 eq.

2006) Org. S. (2002) Angew. , Int. , 41, 164–166. Liu, G. S. (2007) J. Am. Chem. , 129, 6328–6335. (a) Lu, X. (2005) Top. , and Lu, X. (2002) J. Org. , and Yamaguchi, S. (1997) J. Org. , 62, 776–777. (a) For related transformations of alkynes that afford five-membered nitrogen heterocycles, see: Kozawa, Y. and Mori, M. , and Tamaru, Y. , 38, 3963–3966. Yokoyama, H. and Hirai, Y. (2008) Heterocycles, 75, 2133–2153. E. P. (2002) J. Am. Chem. F. E. (2005) J. Org. , 70, 2859–2861. , and Riva, R. (2008) J.

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