Catalytic in Organic Syntheses by Paul Nels Rylander

By Paul Nels Rylander

"Contains the complaints of the ... convention on Catalysis in natural Syntheses.".

summary: "Contains the lawsuits of the ... convention on Catalysis in natural Syntheses."

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9 5 g m . / c m . ^ and the p o r o s i t y o r f r a c t i o n a l p o r i volume (Θ) was a b o u t 0 . 5 0 . S i n c e t h e d e n s i t y o f e t h a n o l (p-j ) a t r e a c t i o n c o n d i t i o n s i s a b o u t 0 . 7 8 g m . / c m . 3 ( 0 . 9 5 + 0 . 5 χ 0 . 7 8 ) . 0 c e n t i p o i s e s , or 0 . 0 1 g m . / c m . s e c . S i n c e the c o n c e n ­ t r a t i o n o f n i t r o b e n z e n e i n the l i q u i d i s r e l a t i v e l y s m a l l (^4 mole % ) , the d e n s i t y and v i s c o s i t y o f the l i q u i d w i l l be a s ­ sumed to be the same a s t h o s e o f p u r e e t h a n o l .

C . , 259 ( 1 9 7 2 ) D a m k o h l e r , G . , Chem. I n g . , 3 , 430 ( 1 9 3 7 ) F r a n k - K a m e n e t s k i i , D . A . , Z h u r . T e k h . F i z . , 9 , 1457 ( 1 9 3 9 ) M e a r s , D . E . , J . C a t . , 2 0 , 127 ( 1 9 7 1 ) R e i d , R . C . , S h e r w o o d , T . K . , " P r o p e r t i e s o f G a s e s and L i q u i d s " , 2nd. e d . Y. (1966) S a t t e r f i e l d , C . N . , "Mass T r a n s f e r i n Heterogeneous C a t a l y ­ s i s " , MIT P r e s s , C a m b r i d g e , M a s s .

3 ( 0 . 9 5 + 0 . 5 χ 0 . 7 8 ) . 0 c e n t i p o i s e s , or 0 . 0 1 g m . / c m . s e c . S i n c e the c o n c e n ­ t r a t i o n o f n i t r o b e n z e n e i n the l i q u i d i s r e l a t i v e l y s m a l l (^4 mole % ) , the d e n s i t y and v i s c o s i t y o f the l i q u i d w i l l be a s ­ sumed to be the same a s t h o s e o f p u r e e t h a n o l . 5 C o n s i d e r t h a t H2 i s the s p e c i e s b e i n g t r a n s p o r t e d . The d i f f u s i o n c o e f f i c i e n t o f H2 i n e t h a n o l (D/\) i s a b o u t 5 .

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